In my previous post I mentioned that I'm building a Linked Data CMS. One of its components is a rich-text editor that allows the creation (and embedding) of structured markup.
An earlier version supported limited Microdata annotations, but now I've switched the mechanism and use an intermediate, but even simpler approach based on HTML5's handy data-* attributes. This lets you build almost arbitrary markup with the editor, including Microformats, Microdata, or RDFa. I don't know yet when the CMS will be publicly available (3 sites are under development right now), but as mentioned, I'd be happy about another pilot project or two. Below is a video demonstrating the editor and its easy customization options.